For IPSec, the common deployment is using Pre-Shared key which needs to be configured at both firewall ends. This is the key used conceptually to encrypt/decrypt. You can look for exact way of encryption/decryption as IPSec IKEv1 goes through phase 1 and phase 2.

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A firewall is a feature on a network that blocks or prevents unwanted access. Firewalls have evolved rapidly over the past 20 years and are nothing like what they were when the internet was in its infancy. Most people want a firewall on their network for the sense of security that it provides. Understanding Firewalls for Home and Small Office Use | CISA Jun 17, 2009

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